Resonant-Enhanced Spectroscopy of Molecular Rotations with a Scanning Tunneling Microscope

Resonant-enhanced spectroscopy of molecular rotations with a scanning tunneling microscope.

We use rotational excitation spectroscopy with a scanning tunneling microscope to investigate the rotational properties of molecular hydrogen and its isotopes physisorbed on the surfaces of graphene and hexagonal boron nitride (h-BN), grown on Ni(111), Ru(0001), and Rh(111). The rotational excitation energies are in good agreement with ΔJ = 2 transitions of freely spinning p-H2 and o-D2 molecul...

Atomic and molecular manipulation with the scanning tunneling microscope.

The prospect of manipulating matter on the atomic scale has fascinated scientists for decades. This fascination may be motivated by scientific and technological opportunities, or from a curiosity about the consequences of being able to place atoms in a particular location. Advances in scanning tunneling microscopy have made this prospect a reality; single atoms can be placed at selected positio...

Time-resolved scanning tunneling microscope light emission spectroscopy of Sb2Te3

We have successfully added ps temporal resolution to scanning tunneling microscope (STM) light emission spectroscopy. STM light emission spectra of Sb2Te3 were measured in the configuration that the tip sample gap of the STM is irradiated by a pair of pump and probe laser pulses with a duration less than 2 ps each, and were analyzed as a function of optical delay time between the pump and probe...

Simulating Scanning Tunneling Microscope

Fabrication of silicon nanostructures with a scanning tunneling microscope

A technique is presented for fabricating Si nanostructures with a scanning tunneling microscope operated in air. The process involves the direct chemical modification of a H-passivated Si( 100) surface and a subsequent liquid etch. The chemically modified portions of the surface can withstand a deep ( > 100 nm) liquid etch of the unmodified regions with no etch degradation of the modified surfa...